Thirumalai chemicals limited material safety data sheet sds msds product name. Anhydrous formic acid and acetic anhydride as solvent or additive in nonaqueous titrations article pdf available in pharmazie 609. Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula ch 3 co 2 o. Material safety data sheet for ethyl acetate, product number. If your institution is not listed, please contact your librarian. Safety data sheet eastmantm acetic anhydride version 2. If inhaled if breathed in, move person into fresh air. Sds sodium dodecyl sulphate surfactant mediated cleavage of imines to the. May cause allergic skin reaction, irritation, and tears. Pdf a sun and cui described the synthesis of oxazolones from a mixture of aryl. With digital photography now mainstream, this may now not be as common. Sep 06, 2011 acetic anhydride was used in the conversion of cellulose to cellulose acetate. Acetic acid, glacial alcohol of vinegar carboxylic acid c2 ethanoic acid. Acetic anhydride definition of acetic anhydride by the.
Flinn chemicals, acetic anhydride flinn scientific. Therefore, on leaking of the product onto iron apparatus and hot piplines heating, the place must be thoroughly cleaned with water. Sds of acetic anhydride, safety data sheets, cas 108247. Consumer products manufactured with maleic anhydride as an intermediate are not expected to retain residuals of the chemical at dangerous levels.
It is widely used as an acetylating agent or in chemical synthesis. View or download the acetic anhydride msds material safety data sheet or sds for 822278 from milliporesigma. However, the concentration of free acetic acid in cells is kept at a low level to avoid disrupting the control of. As the name indicates, an acid anhydride is a compound that is related to an acid by the loss of water. Accidental release measures eliminate all ignition sources no smoking, flares, sparks or flames within at least 25m all equipment used when handling the product must be earthed. Reaction of vanillin and acetic anhydride in the presence of acid. View detailed import data, price, monthly trends, major importing countries, major ports of acetic anhydride import data and price of acetic anhydride zauba skip to main content. Acetic anhydride safety data sheet according to the federal final rule of hazard communication revised on 2012 hazcom 2012 p240 groundbond container and receiving equipment p241 use explosionproof ventilating, lighting, electrical equipment p260 do not breathe fume, gas, vapours p264 wash hands thoroughly after handling. Acetic anhydride safety data sheet product name acetic anhydride conforms to regulation ec no.
Safety data sheet msds is obtained unless a current one. Maleic acid and maleic anhydride may form, mostly with iron, pyrophoric products, which at increased temperature may selfignite. The worldwide production of acetic anhydride is a major application, and uses approximately 25% to 30% of the global production of acetic acid. Safety data sheet eastmantm acetic anhydride, reagent grade version 2. Chemtrec 8004249300 outside usa 7035273887 1216 6th ave n. Relevant identified uses of the substance or mixture and uses advised against. Dilute acetic acid and dilute hydrogen can undergo an. First aid measures general advice consult a physician. A read is counted each time someone views a publication summary such as the title, abstract, and list of authors, clicks on a figure, or views or downloads the fulltext.
In rivers, the principal mixing agent is stream turbulence. Maleic anhydride is known as an excellent dienophile in the dielsalder reaction to. Acetic acid, glacial alcohol of vinegar carboxylic acid c2 ethanoic acid ethylic acid methanecarboxylic acid pyroligneous acid vinegar acid. Clean up spills immediately, observing precautions in the protective equipment section. Acetic anhydride is a clear liquid with a pungent, penetrating vinegarlike odor. Keep container tightly closed do not eat, drink or smoke. Place a magnetic stir bar in the flask, and add one drop of 4.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Accidental release measures contain spill and collect, as appropriate. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Acetic anhydride safety data sheet download 27017 msds ghsclp.
Shortterm health effects maleic anhydride may be corrosive to the respiratory tract and may cause serious damage to the eyes. User is solely responsible for investigating and checking the regulatory approval status. As a side note, it is also used in the production of heroin from morphine. Ensure that medical personnel are aware of the materials involved and take precautions to protect themselves. Acetic acid, glacial alcohol of vinegar carboxylic acid c2 ethanoic acid ethylic acid methanecarboxylic acid pyroligneous acid vinegar acid 1. When released into the soil, this material is expected to leach into groundwater. When entering a maleic anhydride in the insulating material of the apparatus, there is. Enter synonyms, trade names or additional information found in section 1. Reaction with water is particularly dangerous in presence with mineral acids e. Containers of this material may be hazardous when empty since they retain product residues vapors, liquid. Show this safety data sheet to the doctor in attendance. Acetic acid vapors may form explosive mixtures with air. Causes respiratory tract, skin, and eye burns and severe burns to mucus membranes. Page 4 of 8 msds acetic acid sparking type tools and equipment, including explosion proof ventil ation.
If seeking medical attention, provide sds document to physician. Other companies are charging thousands of dollars to set up. Identification of the substancemixture and of the company undertaking 1. Acetic anhydride msds 822278 milliporesigma emd millipore. Identification of the substancemixture and of the companyundertaking. Since acetic anhydride is a relatively nonvolatile liquid, direct venting of the vapor to the atmosphere from a hole in a ruptured vessel does not consitiute a significant hazard downwind. Acetic acid 64197 99 100% all concentrations are percent by weight unless ingredient is a gas. Wear appropriate protective eyeglasses or chemical safety goggles as described by oshas eye and face protection regulations in 29 cfr 1910. We ask that users who download significant portions of the database cite the hmdb paper in any. Search results for acetic acid anhydride at sigmaaldrich.
Pharmacopoeia japanese pharmacopoeia buffers, reagents, test solutions jp reagents, test solutions jp ref num. Acetic anhydride definition of acetic anhydride by the free. It is a colorless liquid that smells strongly of acetic acid, which is formed by its reaction with moisture in the air. Do not allow victim to rub eyes or keep eyes closed. The use of ppe personal protective equipment is essential when handling this chemical in an undiluted state. Safety data sheet of 6 infosafe no 1ch0j issue date. Acetic anhydride safety data sheet supersedes revision.
Safety data sheet northwest missouri state university. Striking a balance between basic chemistry and chemical engineering, this uptodate reference discusses important aspects of acetic acid and its major derivatives, including chemistry, methods of preparation and manufacture, and synthesis, as well as current and emerging downstream technologiesthe book provides comprehensive physical property data for compounds and their separation. Acetic anhydride reacts violently on contact with water, steam, methanol, ethanol, glycerol and boric acid. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. Stopper the flask, and stir at room temperature for one hour. Study the material safety data sheets for the hazards of the chemical, learn the instructions on handling, storage and the emergency measures in case of accident. Use proper personal protective equipment as indicated in section 8. Material safety data sheet acetic anhydride section 1 chemical product and company identification msds name. Commonly abbreviated ac 2 o, it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis. Reactions between acetic acid and the following materials are potentially explosive. For example, the reaction of acetic anhydride with ethanol yields ethyl acetate. Chemtrec 8004249300 outside usa 7035273887 1216 6th ave n kent wa 98032 phone. Type part of your institution name for a list of matches.
Acetic anhydride was used in the conversion of cellulose to cellulose acetate. Safety data sheet according to 29cfr19101200 and ghs rev. View detailed import data, price, monthly trends, major importing countries, major ports of acetic anhydride. The main process involves dehydration of acetic acid to give ketene at 700750 c. Keep container tightly closed do not eat, drink or smoke when using this product wash skin thoroughly after handling. Alternatively, the reaction between the acid chloride and a salt of acetic acid e. Acetic anhydride safety data sheet international acetyls company safety data sheet according to regulation ec no. Identification of the substance maleic anhydride cas number 108316 1.
Avoid runoff into storm sewers and ditches which lead to waterways. Cellulose acetate is a component of photographic film. Acetic anhydride msds material safety data sheet or sds, coa and coq, dossiers, brochures and other available documents. Any existing industrial property rights must be observed. A0440pb08, a0440pb17, a048008, a048017, a0480pb08, a0480pb17 synonyms. Acetic anhydride is a carboxylic acid anhydride commonly used as an acetylating agent for amines and alcohols. Acetic anhydride msds download sevron safety software. Acetic anhydride safety data sheet according to federal register vol. The product of the condensation of two molecules of acetic acid is acetic anhydride. This document was uploaded by user and they confirmed that. Standard operating procedure for cornell university.
Striking a balance between basic chemistry and chemical engineering, this uptodate reference discusses important aspects of acetic acid and its major derivatives, including chemistry, methods of preparation and manufacture, and synthesis, as well as current and emerging downstream technologiesthe book provides comprehensive physical property data for compounds and their. Pdf anhydrous formic acid and acetic anhydride as solvent. Pharmacopoeia japanese pharmacopoeia buffers, reagents. Acetic anhydride safety data sheet international acetyls.
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